Symmetric and non-symmetric vortex-antivortex molecules in fourfold superconducting geometry

In submicron superconducting squares in a homogeneous magnetic field, Ginzburg-Landau theory may admit solutions of the vortex-antivortex type, conforming with the symmetry of the sample [Chibotaru et al., Nature 408, 833 (2000)]. Here we show that these fascinating, but never experimentally observed states, can be enforced by artificial fourfold pinning, with their diagnostic features enhanced by orders of magnitude. The second-order nucleation of vortex-antivortex molecules can be driven either by temperature or applied magnetic field, with stable asymmetric vortex-antivortex equilibria found on its path.