We investigate the overdetermined problem given by \begin{equation*} Δu=0 Ω,\quad \frac{\partial u}{\partialν} =σ_1 u \partial Ω, \quad |\nabla u|= \partial Ω, \end{equation*} where is a connected compact Riemannian surface with smooth boundary , and is the first nonzero Steklov eigenvalue of . We prove that this overdetermined problem admits a nontrivial solution if and only if is -homothetic to either the flat unit disk or a flat cylinder for some . This gives a complete answer to the question raised by Payne and Philippin in [Z. Angew. Math. Phys. 42(6), 864-873, 1991] for and arbitrary surfaces. In particular, we completely characterize compact domains in 2-dimensional space forms for which the overdetermined problem is solvable.

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