In this paper, we first study Rota-Baxter Hopf algebras of weight and construct a matched pair of Hopf algebras on every Rota-Baxter Hopf algebra of weight . Then we propose the notion of projection homomorphism pairs on a matched pair of Hopf algebras, and show that every projection homomorphism pair induces a Rota-Baxter Hopf algebra. Conversely, we prove that the matched pair of Hopf algebras on a Rota-Baxter Hopf algebra of weight gives rise to a projection homomorphism pair . Furthermore, we study the Rota-Baxter Hopf algebra structure on that is Rota-Baxter isomorphic to , and investigate the relationship between the Rota-Baxter Hopf algebra structure on and the descendent Rota-Baxter Hopf algebra .

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