Various real-life networks exhibit degree correlations and heterogeneous structure, with the latter being characterized by power-law degree distribution , where the degree exponent describes the extent of heterogeneity. In this paper, we study analytically the average path length (APL) of and random walks (RWs) on a family of deterministic networks, recursive scale-free trees (RSFTs), with negative degree correlations and various , with an aim to explore the impacts of structure heterogeneity on APL and RWs. We show that the degree exponent has no effect on APL of RSFTs: In the full range of , behaves as a logarithmic scaling with the number of network nodes (i.e. ), which is in sharp contrast to the well-known double logarithmic scaling () previously obtained for uncorrelated scale-free networks with . In addition, we present that some scaling efficiency exponents of random walks are reliant on degree exponent .

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