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Hybrid monolayers of clay minerals (hectorite) and Octadecyamine (ODA) were prepared using the Langmuir-Blodgett (LB) technique. Surface pressure-area per molecule isotherm, FTIR and atomic force microscopy were used to confirm and analyze the ODA-hectorite hybrid films. The monolayer thickness is 2 nm and average height, length and width of individual clay platelets ranges between 1.5 to 2 nm, 500 to 1250 nm and 100 to 115 nm respectively. The surface coverage was more than 80%.

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