Each Ann-category \A is equivalent to an Ann-category of the type (R,M),
where M is an R-bimodule. The family of constraints of A induces a {\it
structure} on (R,M). The main result of the paper is:
- {\it There exists a bijection between the set of structures on (R,M) and
the group of Mac Lane 3-cocycles ZMaL3(R,M).}
- {\it There exists a bijection between C(R,M) of congruence classes of
Ann-categories whose pre-stick is of the type (R,M) and the Mac Lane
cohomology group HMaL3(R,M).}