In 1970, Walkup completely described the set of -vectors for the four 3-manifolds , , , and . We improve one of Walkup’s main restricting inequalities on the set of -vectors of 3-manifolds. As a consequence of a bound by Novik and Swartz, we also derive a new lower bound on the number of vertices that are needed for a combinatorial -manifold in terms of its -coefficient, which partially settles a conjecture of K"uhnel. Enumerative results and a search for small triangulations with bistellar flips allow us, in combination with the new bounds, to completely determine the set of -vectors for twenty further 3-manifolds, that is, for the connected sums of sphere bundles $(S^2 \times S^1)^{# k}(S^2 twist S^1)^{# k}k=2,3,4,5,6,7,8,10,11,14$. For many more 3-manifolds of different geometric types we provide small triangulations and a partial description of their set of -vectors. Moreover, we show that the 3-manifold RP^3 # RP^3 has (at least) two different minimal -vectors.

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