The interplay between different ordered phases, such as superconducting, charge or spin ordered phases, is of central interest in condensed matter physics. The very recent discovery of superconductivity with a remarkable T= 26 K in Fe-based oxypnictide La(OF)FeAs is a surprise to the scientific community\cite{Kamihara08}. The pure LaOFeAs itself is not superconducting but shows an anomaly near 150 K in both resistivity and dc magnetic susceptibility. Here we provide combined experimental and theoretical evidences showing that the anomaly is caused by the spin-density-wave (SDW) instability, and electron-doping by F suppresses the SDW instability and recovers the superconductivity. Therefore, the La(OF)FeAs offers an exciting new system showing competing orders in layered compounds.

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