We report a precise measurement of the masses of the and baryons using a data sample of 414 fb collected by the Belle collaboration at the KEKB collider. The states are observed in the decay modes, while the are reconstructed in the decay modes. The following mass splittings are determined: $m_{\Xi_c(2645)^+} - m_{\Xi_c(2645)^0} = (-0.1 \pm 0.3 ({\rm stat}) \pm 0.6 {(\rm syst})) {\rm MeV}/{\rm c}^2m_{\Xi_c(2815)^+} - m_{\Xi_c(2815)^0} = (-3.4 \pm 1.9 ({\rm stat}) \pm 0.9 {(\rm syst})) {\rm MeV}/{\rm c}^2$ with a much better precision than the current world averages. We also observe a new decay mode, $\Xi_c(2980)^{0,+} \to \Xi_c(2645)^{+,0}\pi^{-,+}$.

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