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Spin precession in Rubidium atoms is investigated through a pump-probe technique. The excited wave packet corresponds to a precession of spin and orbital angular momentum around the total angular momentum. We show that using shaped laser pulses allows us to control this dynamics. With a Fourier transform limited pulse, the wave packet is initially prepared in the bright state (coupled to the initial state) whereas a pulse presenting a step in the spectral phase prepares the wave packet in the dark state (uncoupled to the initial state).

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