A -dimensional Lie group equipped with a left invariant symplectic form is called a symplectic Lie group. It is well-known that induces a left invariant affine structure on . Relatively to this affine structure we show that the left invariant Poisson tensor corresponding to is polynomial of degree 1 and any right invariant -multivector field on is polynomial of degree at most . If is unimodular, the symplectic form is also polynomial and the volume form is parallel. We show also that any left invariant tensor field on a nilpotent symplectic Lie group is polynomial, in particular, any left invariant Poisson structure on a nilpotent symplectic Lie group is polynomial. Because many symplectic Lie groups admit uniform lattices, we get a large class of polynomial Poisson structures on compact affine solvmanifolds.

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