Optical Excitation of Nuclear Spin Coherence in Tm3+:YAG

A thulium-doped crystal is experimentally shown to be an excellent candidate for broadband quantum storage in a solid-state medium. For the first time, nuclear spin coherence is optically excited, detected and characterized in such a crystal. The lifetime of the spin coherence – the potential storage entity – is measured by means of Raman echo to be about 300 $\mu$s over a wide range of ground state splittings. This flexibility, attractive for broadband operation, and well fitted to existing quantum sources, results from the simple hyperfine structure, contrasting with Pr- and Eu- doped crystals.