X-ray Irradiation-induced Carrier Doping Effects in Organic Dimer-Mott Insulators

We report X-ray irradiation-induced carrier doping effects on the electrical conductivity in the organic dimer-Mott insulators $\kappa$-(ET)${}_2$$X$ with $X=$ Cu[N(CN)${}_2$]Cl and Cu${}_2$(CN)${}_3$. For $\kappa$-(ET)${}_2$Cu[N(CN)${}_2$]Cl, we have observed a large decrease of the resistivity by 40 % with the irradiation at 300 K and the metal-like temperature dependence down to about 50 K. The irradiation-induced defects expected at the donor molecule sites might cause a local imbalance of the charge transfer in the crystal. Such molecular defects result in the effective doping of carriers into the half-filled dimer-Mott insulators.