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For a quantum Markov semigroup on the algebra with a faithful invariant state , we can define an adjoint with respect to the scalar product determined by . In this paper, we solve the open problems of characterising adjoints that are also a quantum Markov semigroup and satisfy the detailed balance condition in terms of the operators in the Gorini Kossakowski Sudarshan Lindblad representation of the generator of . We study the adjoint semigroup with respect to both scalar products and $<a,b> = \tr(\rho^{1/2} a^* \rho^{1/2}b)$.

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