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We study classical twists of Lie bialgebra structures on the polynomial current algebra , where is a simple complex finite-dimensional Lie algebra. We focus on the structures induced by the so-called quasi-trigonometric solutions of the classical Yang-Baxter equation. It turns out that quasi-trigonometric -matrices fall into classes labelled by the vertices of the extended Dynkin diagram of . We give complete classification of quasi-trigonometric -matrices belonging to multiplicity free simple roots (which have coefficient 1 in the decomposition of the maximal root). We quantize solutions corresponding to the first root of .

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