Surface effects on the orbital order in the single layered manganite La0.5Sr1.5MnO4

We report the first observation of orbital truncation rods' -- the scattering arising from the termination of bulk orbital order at the surface of a crystal. The x-ray measurements, performed on a cleaved, single-layered perovskite, La0.5Sr1.5MnO4, reveal that while the crystallographic surface is atomically smooth, the orbital surface’ is much rougher, with an r.m.s. deviation from the average `surface’ of ~0.7nm. The temperature dependence of this scattering shows evidence of a surface-induced second order transition.