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A general formalism is used to express the long-range potential energies in inverse powers of the separation distance between two like atomic or molecular systems with symmetries. The long-range molecular interaction coefficients are calculated for the molecular symmetries , , and , arising from the following interactions: He()–He(), He($2 ^1P2 ^3P2 ^3P2 ^3P$). The electric quadrupole-quadrupole term, , the van der Waals (dispersion) term , and higher-order terms, , and , are calculated using accurate variational wave functions in Hylleraas coordinates with finite nuclear mass effects. A comparison is made with previously published results where available.

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