Context: Superbursts are energetic explosions in the crusts of neutron stars in Low-Mass X-ray Binaries (LMXBs). At temperatures above 4 GK, photodisintegration of heavy rp-process ashes may play a major role alongside C fusion. Aims: We investigate how photodisintegration of rp-process ashes affects superburst properties and the initial C abundance required for ignition. Methods: We simulate superbursts with MESA v.24.08.1. Besides the canonical fuel of C and Fe, we test different C abundances mixed with scaled rp-process ashes. Results: Superbursts can ignite with only C when the remaining consists of rp-process ashes. Their luminosity is comparable to that of the canonical fuel, whereas C mixed with Fe yields lower luminosity. Fe remains the most abundant ash nuclide. Although photodisintegration drives nucleosynthesis, neutron, proton and alpha captures release energy at late times. We also find that nuclides or Ne help reduce the C abundance needed for ignition. Conclusions: The composition of accreted material - not just its C content - substantially affects superburst ignition, luminosity and nucleosynthesis.

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