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We establish the existence and qualitative properties of nontrivial solutions for a class of Hartree-Fock type systems defined over the whole space . By introducing a suitable Nehari-Pohozaev manifold, we prove the existence, regularity and we describe the asymptotic behavior of solutions with respect to the interaction parameter . In particular, we show that the system admits either a vector ground state or a semitrivial ground state solution, depending on the magnitude of .

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