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By means of -representation, we investigate the Wishart-Laguerre -ensemble and present a compact expression for Catalan polynomials. For a special Nekrasov partition function associated with the Wishart-Laguerre -ensemble, we show that it can be expressed as a exponential form of the special Catalan polynomials. Furthermore, we make a rule to calculate the Catalan polynomials by means of Feynman diagrams and present another expression for Catalan polynomials. We also establish the connection between certain Catalan polynomials and knot theory.

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