HD~158485 is an A-type ~Scuti star in the CALSPEC network and the JWST absolute-flux calibration program. Gaia DR3 assigns it a binary classification probability close to unity but provides no orbital solution. Using TESS observations from Sectors 14–26, 40–41, 47–60, and 73–86, we measure the pulsation phases of six ~Scuti modes. The frequencies form two groups with opposite light-travel-time delays, revealing two pulsating components. A direct light-curve forward model yields an orbital period of ~d, eccentricity , projected light-time amplitudes of and ~s, and a dynamical mass ratio of . A blind prediction based only on the first two long TESS campaigns reproduces the third campaign without updating the orbital parameters, with a Pearson correlation coefficient of . Its held-out rms is 83.8~s, compared with 289.9~s when the period is fixed at 365.25~d. A 5.15- Hipparcos–Gaia EDR3 proper-motion anomaly independently indicates unresolved astrometric motion. The unresolved companion can also affect spectrophotometric predictions: a conditional PB2-constrained two-atmosphere model differs from the corresponding single-star atmosphere prediction by 1.6% over 1–5~m and 2.5% over 5–28~m. HD~158485 therefore shows that a calibration-relevant binary can lack a catalogued orbital solution while two independent pulsation clocks reveal and measure its orbit.

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