Consider the Mathieu operator for fixed . For large enough , the periodic ( even) or anti-periodic ( odd) problem on has exactly two algebraically simple eigenvalues in the disc . We prove that, as , , where the sign depends on the labelling. For real with , this difference is the length of the th spectral gap. Expanding the exponential determines the relative corrections of orders to , beyond the correction obtained by Anahtarci and Djakov (2012) with a relative remainder. By isospectrality, the same formula holds for the potential with .

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