We aim to provide a cookbook for purely astrometric selection of quasars with Gaia DR3 and to provide an example of its use for the identification of very luminous quasars. We analyse the Gaia DR3 astrometry of confirmed quasars and stationary sources. We show that the proper motion signal to noise follows a Rayleigh-like distribution. We also show the importance of properly taking into account the correlation between proper motions in right ascension and declination, as well as the non-linear error propagation. We adopt the Mahalanobis distance to the null proper-motion hypothesis. A scaled distribution with and scale is fitted to Gaia-CRF3; the corresponding Gaussian-equivalent threshold is . The final criteria combine this with the parallax condition and . Applying the new criteria to the SDSS DR16Q confirmed quasars, the recovery rate is . The suggested purely astrometric selection significantly improves both completeness and purity compared to other strategies used in the literature, reaching a quasar purity of approximately ( Gaussian-equivalent). It can be used to improve the selection purity and completeness for future quasar surveys. As an example, we use the suggested strategi to locate 24 very bright quasars without redshifts in the literature. Our proposed astrometric selection strategy recovers 95% of known quasars. Its potential use for new discoveries is demonstrated by the identification of 24 very luminous quasars. Ten of these are new discoveries and for an additional seven we correct the redshifts determined by other methods.}

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