Testing the horizon properties of astrophysical black holes is a central goal of gravitational-wave astronomy. The recently identified Direct Wave (DW), a prompt non-quasinormal component of GW250114, provides a new probe of near-horizon physics. While it remains unclear whether the DW itself carries horizon information, we show that it enables a novel null test of horizon reflectivity. If the remnant is an exotic compact object (ECO) with a partially reflecting surface, inward plunge radiation is reflected and leaks back through the gravitational potential barrier, producing a delayed DW echo whose amplitude is set by the surface reflectivity (). We construct the corresponding echo template, normalized by the observed DW, and search for it in quasinormal-mode-filtered data. We find no evidence for an echo () and obtain the 90% credible bound , corresponding to a reflected energy fraction below , for surfaces from to a Planck length from the would-be horizon. Our method thus turns the prompt ringdown signal into a direct test of horizon reflectivity.

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