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We prove an invariant identity relating the curvature operators of the first and second kind in dimension four. Under the natural identification , the trace-free Ricci tensor contributes through a single commutator term. As a consequence, we relate the curvature operator of the second kind on products of unit self-dual and anti-self-dual two-forms to biorthogonal sectional curvature. We then classify closed oriented four-manifolds satisfying , where denotes the maximum biorthogonal sectional curvature and is the scalar curvature. The classification includes the cases in which the scalar curvature vanishes.

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