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For a family of the orthogonal type Quantum Matrix algebras we establish an analogue of the Cayley–Hamilton theorem. The form of the Cayley-Hamilton identity is different in three cases. First, the cases of odd () and even () heights are different. Second, for even height orthogonal Quantum Matrix algebra we derive two versions of the Cayley–Hamilton theorem, one for its positive component and another one for the negative component . In each case we introduce the spectral parameterization of the coefficients of the Cayley–Hamilton identity by the `eigenvalues’ of the quantum matrices.

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