We investigate the mass spectra and two-body nonleptonic weak decays of ground-state doubly and triply heavy baryons in a nonrelativistic quark-diquark model. To account for the finite size of the diquark, we generalize the convoluted quark-diquark interaction to unequal-mass diquarks using mass-weighted constituent coordinates and distinct pairwise spin-spin couplings. The resulting Schr{ö}dinger equations provide the baryon masses and wave functions used consistently in the decay calculation. The predicted masses differ from existing lattice QCD results by less than , and our calculated mass of is consistent with recent LHCb observations. The calculated hyperfine splittings are systematically slightly smaller than the lattice values, indicating a residual uncertainty in the spin-dependent interaction. Within the factorization approximation, we evaluate the and transitions with pion or kaon emission. At leading nonrelativistic order, the vector contribution vanishes for the transitions, while both vector and axial contributions enter the channels. The spatial overlaps are substantially smaller than their counterparts. Together with the Cabibbo-Kobayashi-Maskawa hierarchy, this reduces the corresponding width by approximately two orders of magnitude. In the charm transitions, the leading dependence enhances the suppression of kaon emission. In bottom transitions with a larger energy release, the smaller relative phase-space difference brings the ratios close to the scaling determined by the Cabibbo-Kobayashi-Maskawa elements and meson decay constants. These results provide benchmark estimates for future studies of multiply heavy baryons and quantify the role of recoil dynamics within the finite-size quark-diquark framework.

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