We characterize bound entanglement in bipartite qutrit systems by combining the Positive Partial Transpose (PPT) criterion with a structural, non-completely positive map. Focusing on a comprehensive three-parameter bipartite qutrit family , we present an exact analytical and geometric partitioning of the physical state space simplex. We derive the closed-form quadratic boundary governing the leaf-like PPT region over the domain , and identify the exact linear threshold that characterizes the PPT bound entangled sub-region. This family strictly generalizes the well-known Horodecki bound entangled states, which appear as a single slice of the three-dimensional leaf. Applying the structural map to this decomposition, we show that it certifies bound entanglement throughout the entire threshold region, accounting for of the total PPT leaf area.

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