We explore the frontier beyond the recently discovered barrier represented by the \emph{quantum automorphism group} in the classification theory of planar graph homomorphisms . We show that analyzing the spectral relations of can prove #P-hardness when traditional vertex separation and domain-reduction methods with planar edge gadgets provably fail due to the barrier. We prove two criteria of #P-hardness for : a spectral criterion and a determinant criterion. It is known that the core problem for the classification of for nonnegative matrices is for positive definite entry-wise positive matrices. We use the spectral criterion to show that is #P-hard for all circulant matrices of prime order , while for it is precisely the matchgate case and is P-time computable by the FKT algorithm (for planar perfect matching). We also prove a complexity dichotomy for problems defined by tensor products of 2 by 2 matrices. This gives a complete complexity classification for this class of matrices, and the FKT algorithm together with a holographic transformation is \emph{universal}—every is either (1) P-time computable over all graphs, or (2) #P-hard in general but P-time computable over planar graphs, or (3) #P-hard over planar graphs; furthermore, in (2) consists of precisely those computable by FKT with a holographic transformation.

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