spin correlations originating from theoretical models assuming on one side toponium bound state formation in proton-proton collisions at 13 TeV are compared against predictions from non-relativistic QCD ressumation effects via Green’s function formalism that go beyond the perturbative baseline with no bound state but could justify extra yield of events in the mass spectrum recently observed by ATLAS and CMS Collaborations, still awaiting an explanation. Toponium production comprises two scenarios, a simplified Effective Field Theory (EFT) with decays and an additional model with scalar and vector toponium states with and decays. Experimental measurements on system are added to the comparisons. Fitted diagonal spin correlation , , matrix terms show a relative increase in value ranging from 200%-2330% for toponium decays with respect the perturbative NLO baseline. Relative contribution from resummation effect ranges from 0.6% to 10.4% and its combination with perturbative baseline improves agreement with Data distributions, with value reduced by 4.5%-60.0% . Equivalent fitted cross-section for resummation effect , ranges from 7.3 to 9.1 pb in consistency with excess yield reported by LHC experiments. 50 pb range is excluded at 95% C.L. A classifier performing at detector level achieves a ROC curve area of leading to toponium signal to background significances over 55. These results indicate that efficient isolation of observed excess events from background is feasible and a characterisation via spin correlation measurements would reveal their consistency with either toponium production or non-relativistic effects beyond the perturbative baseline.

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