Device-independent quantum key distribution (DIQKD) can guarantee security without trusting the internal workings of the measurement devices, but extending it to fiber networks demands high-quality entanglement, reliable heralding, and faithful photon transmission simultaneously. Here, we address these requirements in an event-ready asymmetric atom-photon architecture implemented over of spooled telecom fiber. A single trapped ion forms one party of the protocol while a single transmitted photon measured at the remote station forms the other. Double quantum frequency conversion and active polarization stabilization preserve the atom-photon quantum correlation across the full link. We obtain a Clauser-Horne-Shimony-Holt parameter of , exceeding the threshold required for a positive asymptotic secret-key fraction under the DIQKD model used. Within the same asymptotic model, this corresponds to a conservative estimate of 69 secret-key bits out of 10908 detected Bell states. The demonstrated architecture establishes a route towards DIQKD in heterogeneous, repeater-compatible quantum networks.

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