In this article, we study the long-time behavior of a finite-volume discretization for a nonlinear kinetic reaction model involving two interacting species. Building upon the seminal work of [Favre, Pirner, Schmeiser, ARMA, 2023], we extend the discrete exponential convergence to equilibrium result established in [Bessemoulin-Chatard, Laidin, Rey, IMAJNA, 2025], which was obtained in a perturbative framework using weighted estimates. The analysis applies to a broader class of exponentially decaying initial data, without requiring proximity to equilibrium, by exploiting the properties of the Boltzmann entropy. The proof relies on the propagation of the initial bounds, derived from monotonicity properties of the scheme, allowing controlled linearizations within the nonlinear entropy estimates. Moreover, we show that the time-discrete dissipation inherent to the numerical scheme plays a crucial stabilizing role, providing control over the nonlinear terms.

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