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In this paper, we study the Liouville equation with a nonlinear Neumann boundary condition \begin{equation*} \begin{cases} -Δu = Ke^{2u} & ^{2},\[2mm] \dfrac{\partial u}{\partial ν}+λ= ke^{u} & \partial^{2}, \end{cases} \end{equation*} where , are constants, and denotes the outward unit normal on . We establish a classification of all smooth solutions to the equation. Our approach is a boundary-adapted P-function method which treats all signs of and within a unified framework. As applications of the classification result, we establish a family of sharp Sobolev-trace-type inequalities encompassing the classical Lebedev–Milin inequality, together with a corresponding deficit estimate.

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