High quality factor () and overtone operation enable narrow-linewidth acoustic devices with multiple discrete frequencies in a single cavity. Maintaining both high and sufficient electromechanical coupling at higher mode orders remains challenging. Here, we demonstrate a bimorph periodically poled piezoelectric film (P3F) lithium niobate (LN) platform for high-order thickness-shear (TS) overtone excitation. The device comprises a bonded 80-m-thick single-crystal X-cut LN bimorph with opposite polarizations, patterned top and floating bottom electrodes, and a suspended air cavity. The P3F configuration mitigates charge cancellation from the alternating stress distribution of higher-order TS modes, enabling measurable coupling across a broad sequence of overtones. The thick LN acoustic cavity and increasingly confined high-order mode profiles support low-loss operation. Measured TS overtones extend to 1.75 GHz. At room temperature, representative overtones at 0.77 and 0.89 GHz exhibit 3-dB values of 11,338 and 11,917, corresponding to products of and Hz, respectively. Cooling from 297 to 12 K systematically enhances , yielding a peak 3-dB of 20,507 at 779 MHz and a maximum product of Hz at 1.379 GHz. These results establish bimorph P3F LN as a promising platform for high-, frequency-scalable micro-acoustic resonators in the sub-GHz and low-GHz regimes.

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