In this paper, we study the nonlinear boundary value problem \begin{equation*} \begin{cases} -Δu=e^{2u},& \mbox{in } {},\ \frac{\partial u}{\partialν}+λ=e^u ,& \mbox{on } {^{1}}, \end{cases} \end{equation*} where is the unit disk, is a constant and denotes the outer unit normal on . For , we establish a complete classification of smooth solutions. For , we prove a dichotomy between radial solutions and nonradial solutions. We develop a Hardy-Wronskian boundary rigidity method that transforms the nonlinear boundary value problem into a spectral rigidity problem for normalized holomorphic frames. This method exploits the complex-analytic structure of the Liouville equation with a Robin boundary condition and provides a new rigidity framework for related two-dimensional elliptic boundary value problems.

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