We show that wavelength measurements of individual detected optical photons may provide additional information about gamma-ray energy deposited in a CeBr crystal when the detected-photon-count distributions overlap for nearby gamma-ray energies. Monoenergetic 662 and 629 keV gammas are used in a Geant4 simulation of a CeBr crystal. Assuming a light yield of photons/MeV, a wavelength-independent photon-detection efficiency of 30%, and a wavelength resolution of nm, we find that the fraction of photons reconstructed above 385 nm gives an event-level separation of 2 standard deviations between the 662 and 629 keV event populations selected within the same 1%-wide detected-photon-count interval. No timing or reconstructed interaction-position information is used. The result demonstrates, within the present simulation model, that event-dependent optical spectra can retain energy information beyond an undifferentiated photon count.

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