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We develop bar cohomology of link complements as an invariant of links in homology spheres. In this setting, bar cohomology is a Hopf algebra which is calculable using surfaces and their intersection curves in a link complement. In this first in a sequence of works, we introduce the invariant and show that it defines a canonical subspace of the tensor Hopf algebra, which already encodes information about Milnor’s link invariants and provides geometrically significant information beyond them.

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