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We study the critical biharmonic equation on a complete, connected, and non-compact Riemannian manifold of dimension with non-negative Ricci curvature. We establish an optimal pointwise second-order derivative estimate by Bernstein’s method and the continuity method. Using invariant tensors, we derive a differential inequality that yields a rigidity result. More precisely, if there exists a positive finite energy solution, then the manifold is isometric to the Euclidean space , and the solution is given by

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