In this paper, we establish a Fefferman–Stein inequality in terms of area function and non-tangential maximal function associated with the Schrödinger operator on stratified Lie groups , where denotes the sub-Laplacian on and is a nonnegative locally integrable function. As an application, we extend this inequality to the tensor product of two stratified Lie groups and develop atomic decompositions associated with the Schrödinger operator for functions in the Orlicz space Using these atomic decompositions, we further prove weak-type endpoint estimates for the area integral operator and the Riesz transforms associated with the Schrödinger operator on thereby extending the celebrated result of R.,Fefferman and E.M.,Stein \cite{FSt1982} to the setting of singular integrals with non-smooth kernels.

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