We investigate the near-threshold structure of the exotic tetraquark candidates and using the effective-range expansion (ERE) and resonance compositeness relations. From the experimental masses and widths, we extract scattering lengths, effective ranges, and molecular compositeness coefficients within a two-channel framework, with uncertainties propagated through Monte Carlo samples. We find large negative scattering lengths, fm for and fm for , and dominant molecular components . The results are robust against variations of compositeness, experimental correlations, and the loop-function subtraction constant. An explicit ERE+CDD-pole analysis finds no physically reasonable bare-state contribution consistent with the observed poles and a natural background. Our results provide strong evidence for predominantly molecular structures of both states and demonstrate the robustness of the ERE approach to near-threshold exotic hadrons.

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