We present a unified calculation of bound and resonant states in purely leptonic Coulomb systems: (), (), (), (), and (). Using an extended stochastic variational method combined with the complex scaling method, we resolve the natural-parity - and -wave spectra. Near their respective thresholds, all three trilepton systems exhibit Gailitis–Damburg sequences generated by and Stark mixing and the resulting inverse-square attraction. Although microscopically distinct from the Efimov effect, this mechanism produces the same inverse-square asymptotics and geometric scaling. The and systems exhibit resonance sequences of comparable density, whereas the produces a much denser spectrum, with 20 resolved members in the channel. In , the deeper states follow molecular Born–Oppenheimer configurations, while the near-threshold spectrum is governed by the atomic structure. In , coupling between threshold-degenerate configurations is essential for a near-threshold bound state. In , the Born–Oppenheimer organization of the resonance spectrum is channel dependent.

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