We classify the entrywise functions that preserve positive semidefiniteness on discrete Green matrices with positive parameters, without requiring the resulting matrix to retain Green structure. For matrices of all orders, the preservers are the zero function and the functions , where is a nonzero finite positive measure and the integral is finite for every . Requiring the resulting matrix to be totally nonnegative reduces the nonzero preservers to , where and . These power functions also preserve positive semidefinite Green structure, while strict Green structure is preserved precisely when . No regularity assumption is needed for these classifications. We also characterize continuously differentiable functions that are entrywise Loewner monotone on every fixed- Green family: this holds precisely when is a positive mixture of nonnegative real powers, with the zero measure allowed.

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