For we construct a closed realization of in whose domain contains the singular mode . The domain, defined via the distributional Caputo composition, is characterized by and ; we prove a Volterra representation for its elements, graph-norm completeness, and that is the adjoint of its zero-trace restriction. Four bounded endpoint traces give an ordinary boundary triplet, so all self-adjoint extensions correspond to Lagrangian planes in , including coupled endpoint conditions. For each we give an exact zero-eigenvalue criterion and, when , an inverse of the form plus an explicit finite-rank correction. Sharp singular-value asymptotics yield , with weak-Schatten endpoint and Weyl asymptotics — now for \emph{every} invertible boundary plane, not only the positive reference problem. As an application we obtain a mild-solution theorem for a Caputo-time diffusion equation in .

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