Twisted primitive group association schemes

We give results on the question of whether the intersection numbers of a primitive group association scheme determine it up to combinatorial isomorphism. For $G=\mathrm{PSL}(2,q)$, where $q$ is an odd prime power with $q=11$ or $q\ge 17$, or $q=2^f$ with $f\ge 3$, we construct a Schur partition that is algebraically isomorphic to the partition of $G$ into conjugacy classes but not combinatorially isomorphic to it. Consequently, the corresponding primitive group association schemes are not determined up to combinatorial isomorphism by their intersection numbers; in particular, they are non-separable. For ${\mathfrak{A}}_6$ and ${\mathfrak{A}}_8$, we also explicitly construct Schur partitions that are algebraically isomorphic to the corresponding partitions into conjugacy classes but not combinatorially isomorphic to them.