Ca-bearing cyanopolyynes in IRC+10216

In recent years, a number of metal-containing, carbon-chain species have been detected in the external circumstellar envelope of the carbon-rich AGB star IRC+10216. The most common metal detected in such species is Mg, for which molecules as large as MgC${}_5$N, MgC${}_5$N${}^{+}$, MgC${}_6$H and MgC${}_6$H${}^{+}$ have been observed. In this paper, we calculate the likely abundances of the Ca-bearing cyanopolyynes, CaC${}_{2n+1}$N for n = 1-4, drawing the conclusion that the observed abundance of CaNC must be made from much larger Ca-terminated cyanopolyyne ions, which requires considerable rearrangement in their dissociative recombination. We pay particular attention to the detectability of CaC${}_3$N whose rotational spectrum has recently been measured.