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We prove that smooth quartic threefolds are symplectically irrational: they cannot be related to projective space by a sequence of symplectic blow-ups, blow-downs, and deformations. This recovers the classical irrationality theorem of Iskovskikh-Manin. The obstruction is constructed from big quantum cohomology, using the multiplicities of eigenvalues of quantum multiplication by the Euler vector field. To prove its invariance, we establish a decomposition theorem for quantum cohomology under symplectic blow-ups, following the work of Iritani.

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